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Triethylamine trihydrofluoride, ca 37% HF, Thermo Scientific Chemicals
Catalog number: L14417.22
100 g, Each
Thermo Scientific Chemicals
Triethylamine trihydrofluoride, ca 37% HF, Thermo Scientific Chemicals
Catalog number: L14417.22
100 g, Each
Quantity
Chemical Identifiers
CAS
73602-61-6
IUPAC Name
trihydrogen triethylamine trifluoride
Molecular Formula
C6H18F3N
InChI Key
IKGLACJFEHSFNN-UHFFFAOYSA-N
SMILES
[H+].[H+].[H+].[F-].[F-].[F-].CCN(CC)CC
Specifications
Specification SheetAssay from Supplier's CofA
21.3-28.0% (w/w) 'free' HF content
Appearance (Color)
Clear colorless to brown
Assay from Supplier's CofA
32-43% total HF content
Form
Liquid
Description
Triethylamine trihydrofluoride acts as a mild and selective fluorinating agent used in the synthesis of acid fluorides and alkyl fluorides. It is also used in the synthesis of vicinal difluorides from epoxides, 3-fluoroazetidine. It is utilized as a selective reagent for the cleavage of O-silyl groups in carbohydrates, nucleotides and cyanohydrins. It is actively involved in the electrochemical fluorodeiodination of alkyl iodides and fluorodesilylation in beta-lactams.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Applications
Triethylamine trihydrofluoride acts as a mild and selective fluorinating agent used in the synthesis of acid fluorides and alkyl fluorides. It is also used in the synthesis of vicinal difluorides from epoxides, 3-fluoroazetidine. It is utilized as a selective reagent for the cleavage of O-silyl groups in carbohydrates, nucleotides and cyanohydrins. It is actively involved in the electrochemical fluorodeiodination of alkyl iodides and fluorodesilylation in beta-lactams.
Solubility
Miscible with water, chloroform and hexanes.
Notes
Hygroscopic. Incompatible with strong oxidizing agents and glass.
Triethylamine trihydrofluoride acts as a mild and selective fluorinating agent used in the synthesis of acid fluorides and alkyl fluorides. It is also used in the synthesis of vicinal difluorides from epoxides, 3-fluoroazetidine. It is utilized as a selective reagent for the cleavage of O-silyl groups in carbohydrates, nucleotides and cyanohydrins. It is actively involved in the electrochemical fluorodeiodination of alkyl iodides and fluorodesilylation in beta-lactams.
Solubility
Miscible with water, chloroform and hexanes.
Notes
Hygroscopic. Incompatible with strong oxidizing agents and glass.
RUO – Research Use Only
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