Thermo Scientific™

Pyridinium dichromate, 98%, Thermo Scientific Chemicals

Catalog number: L15132.22
100 g, Each
Thermo Scientific™

Pyridinium dichromate, 98%, Thermo Scientific Chemicals

Catalog number: L15132.22
100 g, Each
Quantity
Catalog number: L15132.22
Price (USD)
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Chemical Identifiers

CAS
20039-37-6
IUPAC Name
[(hydroxydioxochromio)oxy]chromiumoylol; bis(pyridine)
Molecular Formula
C10H12Cr2N2O7
InChI Key
RCBVKBFIWMOMHF-UHFFFAOYSA-L
SMILES
C1=CC=NC=C1.C1=CC=NC=C1.O[Cr](=O)(=O)O[Cr](O)(=O)=O
Appearance (Color)
Orange to brown
Assay (Iodometric Titration)
≥97.5 to ≤102.5%
Form
Crystals or powder or crystalline powder
Identification (FTIR)
Conforms

Description

Pyridinium dichromate acts as a strong oxidizing agent used in the conversion of primary alcohols and secondary alcohols to aldehydes and ketones respectively. It plays an important role in the oxidation of unsaturated tertiary alcohols, silyl ethers, the carbon-boron bond, and oximes. Further, it is used in the conversion of acetals to esters and didehydroketones to enones in the presence of tert-butyl hydroperoxide.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Pyridinium dichromate acts as a strong oxidizing agent used in the conversion of primary alcohols and secondary alcohols to aldehydes and ketones respectively. It plays an important role in the oxidation of unsaturated tertiary alcohols, silyl ethers, the carbon-boron bond, and oximes. Further, it is used in the conversion of acetals to esters and didehydroketones to enones in the presence of tert-butyl hydroperoxide.

Solubility
Soluble in water, dimethyl formamide, dimethyl sulfoxide and acetonitrile. Slightly soluble in dichloromethane, chloroform and acetone. Insoluble in hexane, ether and ethyl acetate.

Notes
Hygroscopic. Incompatible withorganic materials and powdered metals.
WARNING: Cancer and Reproductive Harm – www.P65Warnings.ca.gov
RUO – Research Use Only

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