Thermo Scientific Chemicals

Dess-Martin periodinane, Thermo Scientific Chemicals

Catalog number: L15779.03
1 g, Each
Thermo Scientific Chemicals

Dess-Martin periodinane, Thermo Scientific Chemicals

Catalog number: L15779.03
1 g, Each
Quantity
Catalog number: L15779.03
also known as L15779-03
Price (USD)
Quantity
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Chemical Identifiers

CAS
87413-09-0
IUPAC Name
1,1-bis(acetyloxy)-3-oxo-3H-1λ⁵,2-benziodaoxol-1-yl acetate
Molecular Formula
C13H13IO8
InChI Key
NKLCNNUWBJBICK-UHFFFAOYSA-N
SMILES
CC(=O)O[I]1(OC(C)=O)(OC(C)=O)OC(=O)C2=CC=CC=C12
Appearance (Color)
White
Form
Powder
Assay from Supplier's CofA
≥97.0%
Proton NMR
Conforms to structure

Description

Dess Martin periodinane is used to oxidize primary alcohols to aldehydes and secondary alcohols to ketones. It is also used as an oxidant for complexes with multifunctional alcohols. It is actively involved in the oxidation of N-protected-amino alcohols without epimerization and allylic alcohols.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Dess Martin periodinane is used to oxidize primary alcohols to aldehydes and secondary alcohols to ketones. It is also used as an oxidant for complexes with multifunctional alcohols. It is actively involved in the oxidation of N-protected-amino alcohols without epimerization and allylic alcohols.

Solubility
Soluble in chloroform, acetone, acetonitrile and methylene chloride. Slightly soluble in ether and hexane.

Notes
Store in cool place. Air and moisture sensitive. Incompatible with strong reducing agents, combustible material and water.
RUO – Research Use Only

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