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(R)-(+)-1-Phenylethylamine, 99+%, ee 99+%, Thermo Scientific Chemicals
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Catalog number L19117.06
also known as L19117-06
Price (USD)/ Each
33.90
-
Quantity:
5 g
Price (USD)/ Each
33.90
(R)-(+)-1-Phenylethylamine, 99+%, ee 99+%, Thermo Scientific Chemicals
Catalog numberL19117.06
Price (USD)/ Each
33.90
-
Chemical Identifiers
CAS3886-69-9
IUPAC Name1-phenylethan-1-amine
Molecular FormulaC8H11N
InChI KeyRQEUFEKYXDPUSK-UHFFFAOYNA-N
SMILESCC(N)C1=CC=CC=C1
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Specifications
Specification Sheet
Specification SheetAppearance (Color)Clear colorless to pale yellow
FormLiquid
Assay (GC)≥99.0%
Optical Rotation+30° ± 2° (c=10 in ethanol)
Refractive Index1.5250-1.5280 @ 20°C
(R)-(+)-1-Phenylethylamine is used as an intermediate in organic synthesis. It is also used to determine the enantiomeric purity of acids.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Applications
(R)-(+)-1-Phenylethylamine is used as an intermediate in organic synthesis. It is also used to determine the enantiomeric purity of acids.
Solubility
Miscible with water and chloroform.
Notes
Store in a cool place. Air Sensitive. Incompatible with acids, acid chlorides, acid anhydrides, strong oxidizing agents and carbon dioxide.
(R)-(+)-1-Phenylethylamine is used as an intermediate in organic synthesis. It is also used to determine the enantiomeric purity of acids.
Solubility
Miscible with water and chloroform.
Notes
Store in a cool place. Air Sensitive. Incompatible with acids, acid chlorides, acid anhydrides, strong oxidizing agents and carbon dioxide.
RUO – Research Use Only
General References:
- Both enantiomers are widely used resolving agent for chiral acids. They also find extensive use as chiral auxiliaries in asymmetric synthesis:
- For use in the enantioselective synthesis of ɑ-amino nitriles and amino acids in the Strecker reaction, see: Chem. Ber., 110, 2098 (1977); J. Org. Chem., 48, 5369 (1983). Similarly, the preformed imines can be reacted with Trimethyl silyl cyanide, A19598: Chem. Lett., 331, 737 (1975). Enantioselective synthesis of cyclohexylamines from 2-alkylcyclohexanones via the imine and reduction: Tetrahedron Lett., 22, 2633 (1981); Chem. Ber., 117, 2076 (1984). Enantioselective synthesis of ɑ-aminoacetals from 1,1-dialkoxy-2-propanones: Synthesis, 608 (1989).
- Selivanova, S. V.; Toscano, A.; Abate, C.; Berardi, F.; Müller, A.; Krämer, S. D.; Schibli, R.; Ametamey, S. M. Synthesis and pharmacological evaluation of 11C-labeled piperazine derivative as a PET probe for sigma-2 receptor imaging. Nucl. Med. Biol. 2015, 42 (4), 399-405.
- Alvarado-Beltrán, I.; Maerten, E.; Toscano, R. A.; López-Cortés, J. G.; Baceiredo, A.; Álvarez-Toledano, C. Enantioselective synthesis of 4-alkenoic acids via Pd-catalyzed allylic alkylation: stereocontrolled construction of gamma and delta-lactones. Tetrahedron: Asymmetry 2015, 26 (15-16), 802-809.