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Bismuth(III) trifluoromethanesulfonate, 99%, Thermo Scientific Chemicals
Catalog number: L19687.06
5 g, Each
Thermo Scientific Chemicals
Bismuth(III) trifluoromethanesulfonate, 99%, Thermo Scientific Chemicals
Catalog number: L19687.06
5 g, Each
Quantity
Catalog number: L19687.06
also known as L19687-06
Price (USD)
Special offer:
57.65 61.65 Online priceSave 4.00 (6%)
Ends: 15-Oct-2024
Each
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Chemical Identifiers
CAS
88189-03-1
IUPAC Name
bismuth(3+) tritrifluoromethanesulfonate
Molecular Formula
C3BiF9O9S3
InChI Key
NYENCOMLZDQKNH-UHFFFAOYSA-K
SMILES
[Bi+3].[O-]S(=O)(=O)C(F)(F)F.[O-]S(=O)(=O)C(F)(F)F.[O-]S(=O)(=O)C(F)(F)F
Specifications
Specification SheetAppearance (Color)
White
Form
Powder
Assay (unspecified)
≥98.5% on basis of Fluoride EA (non-U.S. specification)
Assay from Suppliers CofA
≥98.5% (U.S. specification)
Comment
Specification differs for U.S. and non-U.S. material where indicated
Description
Bismuth(III) trifluoromethanesulfonate acts as a catalyst in Friedel-Crafts acylation and cycloisomerization of allene-enol ethers. It behaves as a direct substitution catalyst and involved in the substitution of allylic, propargylic, and benzylic alcohols with sulfonamides, carboxamides and carbamates. Further, it is also used in Mukaiyama aldol reactions.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Applications
Bismuth(III) trifluoromethanesulfonate acts as a catalyst in Friedel-Crafts acylation and cycloisomerization of allene-enol ethers. It behaves as a direct substitution catalyst and involved in the substitution of allylic, propargylic, and benzylic alcohols with sulfonamides, carboxamides and carbamates. Further, it is also used in Mukaiyama aldol reactions.
Solubility
Soluble in organics acetonitrile, dioxane, dimethyl formamide and dimethyl sulfoxide.
Notes
Hygroscopic. Incompatible with strong oxidizing agents.
Bismuth(III) trifluoromethanesulfonate acts as a catalyst in Friedel-Crafts acylation and cycloisomerization of allene-enol ethers. It behaves as a direct substitution catalyst and involved in the substitution of allylic, propargylic, and benzylic alcohols with sulfonamides, carboxamides and carbamates. Further, it is also used in Mukaiyama aldol reactions.
Solubility
Soluble in organics acetonitrile, dioxane, dimethyl formamide and dimethyl sulfoxide.
Notes
Hygroscopic. Incompatible with strong oxidizing agents.
RUO – Research Use Only
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