An ionic liquid, 1-ethyl-3-methylimidazolium bromide is used as reaction medium for the synthesis and crystallization of a coordination polymer, (EMI)[Cd(BTC)]. 1-ethyl-3-methylimidazolium bromide was used as a solvent in [emim] 2 [Cd 2 (btec)Br 2 ]. Form the diene complexation; carbonyl insertion; cycloaddition; reduction and deoxygenation.
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Applications
An ionic liquid, 1-ethyl-3-methylimidazolium bromide is used as reaction medium for the synthesis and crystallization of a coordination polymer, (EMI)[Cd(BTC)]. 1-ethyl-3-methylimidazolium bromide was used as a solvent in [emim] 2 [Cd 2 (btec)Br 2 ]. Form the diene complexation; carbonyl insertion; cycloaddition; reduction and deoxygenation.
Solubility
Soluble in water, dichloromethane, ethanol, acetonitrile. Insoluble in ethyl acetate, ether, and alkane.
Notes
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents, water, moisture.
RUO – Research Use Only
General References:
- Mohammed Taghi Zafarani-Moattar,; Shokat Sarmad. Effect of tri-potassium phosphate on volumetric, acoustic, and transport behaviour of aqueous solutions of 1-ethyl-3-methylimidazolium bromide at T = (298.15 to 318.15) K. The Journal of Chemical Thermodynamics. 2010, 42 (10), 1213-1221.
- Steven D. Chambreau,; Jerry A. Boatz,; Ghanshyam L. Vaghjiani,; Christine Koh,; Oleg Kostko.Thermal Decomposition Mechanism of 1-Ethyl-3-methylimidazolium Bromide Ionic Liquid. J. Phys. Chem. A. 2012 , 116 (24), 5867-5876.