Thermo Scientific Chemicals

Chlorobis(cyclooctene)iridium(I) dimer, Ir nominally 42.9%, Thermo Scientific Chemicals

Catalog number: 044966.06
5 g, Each
Thermo Scientific Chemicals

Chlorobis(cyclooctene)iridium(I) dimer, Ir nominally 42.9%, Thermo Scientific Chemicals

Catalog number: 044966.06
5 g, Each
Quantity
Catalog number: 044966.06
also known as 044966-06
Price (EUR)

Chemical Identifiers

CAS
12246-51-4
IUPAC Name
tetrakis(cyclooctene) diiridium dichloride
Molecular Formula
C32H56Cl2Ir2
InChI Key
CJJIQMGSHWWMCK-UHFFFAOYSA-L
SMILES
[Cl-].[Cl-].[Ir].[Ir].C1CCCC=CCC1.C1CCCC=CCC1.C1CCCC=CCC1.C1CCCC=CCC1
Assay (unspecified)
5.80-6.80% Hydrogen
Assay (unspecified)
6.90-8.90% Chlorine
Assay (unspecified)
41.90-43.90% Carbon

Description

Chlorobis(cyclooctene)iridium(I) dime is used as catalyst for Isomerization-hydroboration reactions with nido-carboranyldiphosphine as stabilizing ligand, Hydrogen peroxide oxidation of hydroxamic acids and their subsequent hetero Diels-Alder cycloaddition reactions, Immobilization of organic functional groups onto solid supports through vinylsilane coupling reactions, Alkylation reactions, Guerbet reaction, Allylic amination reactions in a DNA-diene-iridium(I) hybrid system, Asymmetric hydroamination reactions.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

RUO – Research Use Only

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    Safety and Handling


    Classification of the substance or mixture
    CLP classification - Regulation(EC) No 1272/2008
    Skin Corrosion/Irritation
    Category 2
    Serious Eye Damage/Eye Irritation
    Category 2
    Specific target organ toxicity - (single exposure)
    Category 3
    Label Elements
    Signal Word

    Warning

    Hazard Statements

    H315 - Causes skin irritation

    H319 - Causes serious eye irritation

    H335 - May cause respiratory irritation

    Precautionary Statements

    P261 - Avoid breathing dust/fume/gas/mist/vapors/spray

    P280 - Wear protective gloves/protective clothing/eye protection/face protection

    P302 + P352 - IF ON SKIN: Wash with plenty of soap and water

    P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing