Thermo Scientific Chemicals

1-Trimethylsilyl-1-propyne, 98%, Thermo Scientific Chemicals

Catalog number: B24875.06
5 g, Each
Thermo Scientific Chemicals

1-Trimethylsilyl-1-propyne, 98%, Thermo Scientific Chemicals

Catalog number: B24875.06
5 g, Each
Quantity
Catalog number: B24875.06
also known as B24875-06
Price (EUR)
Quantity
-

Chemical Identifiers

CAS
6224-91-5
IUPAC Name
trimethyl(prop-1-yn-1-yl)silane
Molecular Formula
C6H12Si
InChI Key
DCGLONGLPGISNX-UHFFFAOYSA-N
SMILES
CC#C[Si](C)(C)C
Assay (GC)
≥97.5%
Refractive Index
1.4180-1.4220 @ 20°C
Appearance (Color)
Clear colorless
Form
Liquid

Description

1-Trimethylsilyl-1-propyne is employed in the preparation of alkynyl silane derivatives. It is also used to prepare highly substituted indenes using palladium-catalyzed carboannulation. Further, it plays an important role in the preparation of indenones through a rhodium-catalyzed reaction with 2-bromophenylboronic acids.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
1-Trimethylsilyl-1-propyne is employed in the preparation of alkynyl silane derivatives. It is also used to prepare highly substituted indenes using palladium-catalyzed carboannulation. Further, it plays an important role in the preparation of indenones through a rhodium-catalyzed reaction with 2-bromophenylboronic acids.

Solubility
Miscible with toluene.

Notes
Store in a cool place. Incompatible with strong oxidizing agents and strong bases.
RUO – Research Use Only

Figures

Documents & Downloads

Certificates

    Frequently asked questions (FAQs)

    Citations & References

    Search citations by name, author, journal title or abstract text

    Safety and Handling


    Classification of the substance or mixture
    CLP classification - Regulation(EC) No 1272/2008
    Flammable liquids
    Category 2
    Skin Corrosion/Irritation
    Category 2
    Serious Eye Damage/Eye Irritation
    Category 2
    Specific target organ toxicity - (single exposure)
    Category 3
    Label Elements
    Signal Word

    Danger

    Hazard Statements

    H315 - Causes skin irritation

    H319 - Causes serious eye irritation

    H335 - May cause respiratory irritation

    Physical Hazards

    H225 - Highly flammable liquid and vapor

    Precautionary Statements

    P261 - Avoid breathing dust/fume/gas/mist/vapors/spray

    P280 - Wear protective gloves/protective clothing/eye protection/face protection

    P302 + P352 - IF ON SKIN: Wash with plenty of soap and water

    P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing

    P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking

    P240 - Ground and bond container and receiving equipment