tert-Butyldichlorophosphine, 98%, Thermo Scientific Chemicals
Thermo Scientific Chemicals
tert-Butyldichlorophosphine, 98%, Thermo Scientific Chemicals
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50 g
1 g
Catalog number H27360.18
also known as H27360-18
Price (EUR)/ Each
520,00
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Quantity:
50 g
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Price (EUR)/ Each
520,00
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tert-Butyldichlorophosphine, 98%, Thermo Scientific Chemicals
Catalog numberH27360.18
Price (EUR)/ Each
520,00
-
Add to cart
Chemical Identifiers
CAS25979-07-1
IUPAC Nametert-butyldichlorophosphane
Molecular FormulaC4H9Cl2P
InChI KeyNMJASRUOIRRDSX-UHFFFAOYSA-N
SMILESCC(C)(C)P(Cl)Cl
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SpecificationsSpecification SheetSpecification Sheet
Appearance (Color)White to pale yellow
FormCrystalline or fused solid
Assay (GC)≥97.5%
Proton NMRConforms to structure
Reactant for the synthesis of alkali metal complexes. As intermediates. tert-Butyldichlorophosphine (TBDCP) is used primarily in the preparation of monoand bidentate phosphine ligands in metal complexes for catalytic chiral asymmetric hydrogenations and other asymmetric reactions as well as transition metal coupling reactions. This reagent is also used in the preparation of other phosphines in catalytic polymerization reactions.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Reactant for the synthesis of alkali metal complexes. As intermediates. tert-Butyldichlorophosphine (TBDCP) is used primarily in the preparation of monoand bidentate phosphine ligands in metal complexes for catalytic chiral asymmetric hydrogenations and other asymmetric reactions as well as transition metal coupling reactions. This reagent is also used in the preparation of other phosphines in catalytic polymerization reactions.

Solubility
Reacts with water. Soluble in n-Pentane, n-Hexane, Ether, Toluene,THF. tert-Butyldichlorophosphine is infinitely soluble in hydrocarbon and ethereal solvents.

Notes
Air & Moisture Sensitive. Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents, strong bases, air, water and moisture.
RUO – Research Use Only

General References:

  1. Jonathan J Gammon et. al. Synthesis of P-stereogenic compounds via kinetic deprotonation and dynamic thermodynamic resolution of phosphine sulfides: opposite sense of induction using (-)-sparteine.. Journal of the American Chemical Society. 2010, 132 (39), 13922-13927 .
  2. Heidi Landert et. al. Chiral mixed secondary phosphine-oxide-phosphines: high-performing and easily accessible ligands for asymmetric hydrogenation. Angewandte Chemie. 2010, 49 (38),6873-6876.