Phenylmagnesium bromide, 3M in 2-MeTHF, Thermo Scientific Chemicals
Phenylmagnesium bromide, 3M in 2-MeTHF, Thermo Scientific Chemicals
Thermo Scientific Chemicals

Phenylmagnesium bromide, 3M in 2-MeTHF, Thermo Scientific Chemicals

 
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Quantity:
100 mL
Catalog number H54729.AE
also known as H54729-AE
Price (EUR)/ Each
272,70
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303.00 
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Quantity:
100 mL
Request bulk or custom format
Price (EUR)/ Each
272,70
Online exclusive
303.00 
Save 30,30 (10%)
Add to cart
Phenylmagnesium bromide, 3M in 2-MeTHF, Thermo Scientific Chemicals
Catalog numberH54729.AE
Price (EUR)/ Each
272,70
Online exclusive
303.00 
Save 30,30 (10%)
-
Add to cart
Chemical Identifiers
CAS100-58-3
IUPAC Namebromo(phenyl)magnesium
Molecular FormulaC6H5BrMg
InChI KeyANRQGKOBLBYXFM-UHFFFAOYSA-M
SMILESBr[Mg]C1=CC=CC=C1
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SpecificationsSpecification SheetSpecification Sheet
CommentSolvent: 2-MeTHF
FormLiquid
Concentration2.8-3.2M
Phenyl magnesium bromide is the suitable reagent used for the synthesis of end-functionalized regioregular poly(3-alkylthiophene)s. It may be used for synthesis of  1,3,3-trimethyl-6-phenyl-2-oxabicyclo[2.2.2]octan-6-ol, 6-benzyl-1,3,3-trimethyl-2-oxabicyclo[2.2.2]octan-6-ol, (3-(2-Dithiobenzoatepropionyl)propyl)dimethylmethoxysilane, reversible addition-fragmentation chain transfer polymerization (RAFT)-silane agent, series of o-substituted benzophenones.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Phenyl magnesium bromide is the suitable reagent used for the synthesis of end-functionalized regioregular poly(3-alkylthiophene)s. It may be used for synthesis of  1,3,3-trimethyl-6-phenyl-2-oxabicyclo[2.2.2]octan-6-ol, 6-benzyl-1,
RUO – Research Use Only

General References:

  1. W. H. Urry.; M. S. Kharasch. Factors Influencing the Course and Mechanism of Grignard Reactions. XV. The Reaction of β,β-Dimethylphenethyl Chloride with Phenylmagnesium Bromide in the Presence of Cobaltous Chloride. J. Am. Chem. Soc. 1944, 66 (9),1438-1440.
  2. G. Stucky.; R. E. Rundle. The Constitution of the Grignard Reagent, Phenylmagnesium Bromide Dietherate. J. Am. Chem. Soc. 1964, 87 (22),4825-4830.