Thermo Scientific Chemicals

(1S,2S)-(-)-1,2-Diphenyl-1,2-ethanediamine, 97%, Thermo Scientific Chemicals

Catalog number: L12968.14
25 g, Each
Thermo Scientific Chemicals

(1S,2S)-(-)-1,2-Diphenyl-1,2-ethanediamine, 97%, Thermo Scientific Chemicals

Catalog number: L12968.14
25 g, Each
Quantity
Catalog number: L12968.14
also known as L12968-14
Price (EUR)
Quantity
-
Have Questions?

Chemical Identifiers

CAS
29841-69-8
IUPAC Name
(1S,2S)-1,2-diphenylethane-1,2-bis(aminium)
Molecular Formula
C14H18N2
InChI Key
PONXTPCRRASWKW-KBPBESRZSA-P
SMILES
[NH3+][C@H]([C@@H]([NH3+])C1=CC=CC=C1)C1=CC=CC=C1
Assay (Non-aqueous acid-base Titration)
≥96.0 to ≤104.0%
Appearance (Color)
White to pale cream to cream to yellow
Form
Crystals or powder or crystalline powder or lumps or fused solid
Assay (GC)
≥96.0%
Melting Point (clear melt)
77.0-86.0?C

Description

(1S,2S)-(-)-1,2-Diphenyl-1,2-ethanediamine solvation agent, For synthesis of enantiopure ethylenediamines by chirality transfer (condensation with diketones followed by reductive cleavage), Co-catalyst in the Ru catalyzed enantioselective hydrogenation of aromatic ketones, Versatile ligand for the formation of metal complexes.1 Used in the synthesis of chiral tropocoronands which have potential utility in asymmetric catalysis

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
(1S,2S)-(-)-1,2-Diphenyl-1,2-ethanediamine solvation agent, For synthesis of enantiopure ethylenediamines by chirality transfer (condensation with diketones followed by reductive cleavage), Co-catalyst in the Ru catalyzed enantioselective hydrogenation of aromatic ketones, Versatile ligand for the formation of metal complexes.1 Used in the synthesis of chiral tropocoronands which have potential utility in asymmetric catalysis

Solubility
Insoluble in water.

Notes
Keep container tightly closed. Store in cool, dry conditions in well sealed containers. It is sensitive to air.
RUO – Research Use Only

Figures

Documents & Downloads

Certificates

    Frequently asked questions (FAQs)

    Citations & References

    Search citations by name, author, journal title or abstract text

    Safety and Handling


    Classification of the substance or mixture
    CLP classification - Regulation(EC) No 1272/2008
    Acute oral toxicity
    Category 4
    Acute dermal toxicity
    Category 4
    Skin Corrosion/Irritation
    Category 1
    Serious Eye Damage/Eye Irritation
    Category 1
    Label Elements
    Signal Word

    Danger

    Hazard Statements

    H302 + H312 - Harmful if swallowed or in contact with skin

    H314 - Causes severe skin burns and eye damage

    Precautionary Statements

    P280 - Wear protective gloves/protective clothing/eye protection/face protection

    P301 + P330 + P331 - IF SWALLOWED: rinse mouth. Do NOT induce vomiting

    P302 + P352 - IF ON SKIN: Wash with plenty of soap and water

    P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing

    P310 - Immediately call a POISON CENTER or doctor/physician