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2-Bromopyrimidine, 98+%, Thermo Scientific Chemicals
Catalog number: A13791.22
100 g, Each
Thermo Scientific Chemicals
2-Bromopyrimidine, 98+%, Thermo Scientific Chemicals
Catalog number: A13791.22
100 g, Each
Quantity
Catalog number: A13791.22
also known as A13791-22
Price (EUR)
805,45 Online price
905,00
Each
Quantity
-
Chemical Identifiers
CAS
4595-60-2
IUPAC Name
2-bromopyrimidine
Molecular Formula
C4H3BrN2
InChI Key
PGFIHORVILKHIA-UHFFFAOYSA-N
SMILES
BrC1=NC=CC=N1
Specifications
Specification SheetAppearance (Color)
White to cream or pale yellow or pale brown
Assay (GC)
≥98.0% (non-U.S. specification)
Assay from Suppliers CofA
≥98.0% (U.S. specification)
Comment
Purchased in the U.S. and in other countries
Identification (FTIR)
Conforms (non-U.S. specification)
Description
2-Bromopyrimidine is used in the preparation of 2,7-bis(2-pyrimidyl)-9,9-dihexylfluorene by cross-coupling with 9,9-dihexylfluorene-2,7-diboronic acid. It undergoes microwave-assisted aminocarbonylation at C-2 with palladium and molybdenum hexacarbonyl.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Applications
2-Bromopyrimidine is used in the preparation of 2,7-bis(2-pyrimidyl)-9,9-dihexylfluorene by cross-coupling with 9,9-dihexylfluorene-2,7-diboronic acid. It undergoes microwave-assisted aminocarbonylation at C-2 with palladium and molybdenum hexacarbonyl.
Solubility
Miscible with water.
Notes
Store in a cool place. Incompatible with strong oxidizing agents, strong acids, acid chlorides.
2-Bromopyrimidine is used in the preparation of 2,7-bis(2-pyrimidyl)-9,9-dihexylfluorene by cross-coupling with 9,9-dihexylfluorene-2,7-diboronic acid. It undergoes microwave-assisted aminocarbonylation at C-2 with palladium and molybdenum hexacarbonyl.
Solubility
Miscible with water.
Notes
Store in a cool place. Incompatible with strong oxidizing agents, strong acids, acid chlorides.
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Safety and Handling
Classification of the substance or mixture
CLP classification - Regulation(EC) No 1272/2008
Skin Corrosion/Irritation
Category 2
Serious Eye Damage/Eye Irritation
Category 2
Specific target organ toxicity - (single exposure)
Category 3
Label Elements
Signal Word
Warning
Hazard Statements
H315 - Causes skin irritation
H319 - Causes serious eye irritation
H335 - May cause respiratory irritation
Precautionary Statements
P261 - Avoid breathing dust/fume/gas/mist/vapors/spray
P302 + P352 - IF ON SKIN: Wash with plenty of soap and water
P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
P280 - Wear protective gloves/protective clothing/eye protection/face protection
P332 + P313 - If skin irritation occurs: Get medical advice/attention
P337 + P313 - If eye irritation persists: Get medical advice/attention