Thermo Scientific Chemicals

Boron trifluoride diethyl etherate, 98+%, Thermo Scientific Chemicals

Catalog number: A15275.AP
500 mL, Each
Thermo Scientific Chemicals

Boron trifluoride diethyl etherate, 98+%, Thermo Scientific Chemicals

Catalog number: A15275.AP
500 mL, Each
Quantity
Catalog number: A15275.AP
also known as A15275-AP
Price (EUR)
Quantity
-

Chemical Identifiers

CAS
109-63-7
IUPAC Name
ethoxyethane; trifluoroborane
Molecular Formula
C4H10BF3O
InChI Key
KZMGYPLQYOPHEL-UHFFFAOYSA-N
SMILES
FB(F)F.CCOCC
Form
fuming liquid
Appearance (Color)
Colourless to pale brown
Assay from Supplier's CofA
≥47.0 to ≤49.5 % w/w (as BF3)

Description

Boron trifluoride diethyl etherate is used as a Lewis acid catalyst in Mukaiyama aldol addition, alkylation, acetylation, isomerization, dehydrations and condensation reactions. It is involved in the prepattion of polyethers in polymerization reactions. As a catalyst, it is used in the preparation of cyclopentyl- and cycloheptyl[b]indoles and other diborane. It is also used in sensitive neutron detectors in ionization chambers as well as monitoring radiation levels in earth’s atmosphere.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Boron trifluoride diethyl etherate is used as a Lewis acid catalyst in Mukaiyama aldol addition, alkylation, acetylation, isomerization, dehydrations and condensation reactions. It is involved in the prepattion of polyethers in polymerization reactions. As a catalyst, it is used in the preparation of cyclopentyl- and cycloheptyl[b]indoles and other diborane. It is also used in sensitive neutron detectors in ionization chambers as well as monitoring radiation levels in earth’s atmosphere.

Solubility
Miscible with ether and alcohol.

Notes
Moisture sensitive. Store in cool place. Recommended to use under inet atomosphere. Incompatible with metals, acids, bases, alcohols, alkali metals, oxidizing agents and water. Reacts violently with water.
RUO – Research Use Only

Figures

Documents & Downloads

Certificates

    Frequently asked questions (FAQs)

    Citations & References

    Search citations by name, author, journal title or abstract text

    Safety and Handling


    Classification of the substance or mixture
    CLP classification - Regulation(EC) No 1272/2008
    Flammable liquids
    Category 3
    Acute Inhalation Toxicity - Vapors
    Category 4
    Skin Corrosion/Irritation
    Category 1
    Serious Eye Damage/Eye Irritation
    Category 1
    Specific target organ toxicity - (repeated exposure)
    Category 1
    Label Elements
    Signal Word

    Danger

    Hazard Statements

    H314 - Causes severe skin burns and eye damage

    H332 - Harmful if inhaled

    H372 - Causes damage to organs through prolonged or repeated exposure if inhaled

    Physical Hazards

    H226 - Flammable liquid and vapor

    Precautionary Statements

    P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking

    P280 - Wear protective gloves/protective clothing/eye protection/face protection

    P303 + P361 + P353 - IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower

    P304 + P340 - IF INHALED: Remove person to fresh air and keep comfortable for breathing

    P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing

    P310 - Immediately call a POISON CENTER or doctor/physician