Thermo Scientific Chemicals

4-Methylmorpholine N-oxide monohydrate, 98+%, Thermo Scientific Chemicals

Catalog number: A15996.14
25 g, Each
Thermo Scientific Chemicals

4-Methylmorpholine N-oxide monohydrate, 98+%, Thermo Scientific Chemicals

Catalog number: A15996.14
25 g, Each
Quantity
Catalog number: A15996.14
also known as A15996-14
Price (EUR)
Quantity
-

Chemical Identifiers

CAS
70187-32-5
IUPAC Name
4-methylmorpholin-4-ium-4-olate
Molecular Formula
C5H11NO2
InChI Key
LFTLOKWAGJYHHR-UHFFFAOYSA-N
SMILES
C[N+]1([O-])CCOCC1
Assay (Non-aqueous acid-base Titration)
≥98.0 to ≤102.0% (dry wt. basis)
Appearance (Color)
White to cream
Form
Crystalline powder and/or Lumps
Solution Test
Clear colorless (ethanol, 5%)
Water Content (Karl Fischer Titration)
10-16% (0.7-1.2 waters of hydration)

Description

4-Methylmorpholine N-oxide monohydrate is used as a solvent to prepare cellulose fibers. It is an oxidant and involved in the catalytic OsO4 oxidation of olefins to cis-1,2-diols. It is also involved in ruthenium catalyzed oxidation of alcohols to aldehydes and ketones.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
4-Methylmorpholine N-oxide monohydrate is used as a solvent to prepare cellulose fibers. It is an oxidant and involved in the catalytic OsO4 oxidation of olefins to cis-1,2-diols. It is also involved in ruthenium catalyzed oxidation of alcohols to aldehydes and ketones.

Solubility
Soluble in water.

Notes
Hygroscopic. Store in a cool place. Keep the container tightly closed. Incompatible with strong oxidizing agents.
RUO – Research Use Only

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    Safety and Handling


    Classification of the substance or mixture
    CLP classification - Regulation(EC) No 1272/2008
    Skin Corrosion/Irritation
    Category 2
    Serious Eye Damage/Eye Irritation
    Category 2
    Specific target organ toxicity - (single exposure)
    Category 3
    Label Elements
    Signal Word

    Warning

    Hazard Statements

    H315 - Causes skin irritation

    H319 - Causes serious eye irritation

    H335 - May cause respiratory irritation

    Precautionary Statements

    P280 - Wear protective gloves/protective clothing/eye protection/face protection

    P302 + P352 - IF ON SKIN: Wash with plenty of soap and water

    P304 + P340 - IF INHALED: Remove person to fresh air and keep comfortable for breathing

    P312 - Call a POISON CENTER or doctor if you feel unwell

    P332 + P313 - If skin irritation occurs: Get medical advice/attention

    P337 + P313 - If eye irritation persists: Get medical advice/attention