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Copper(II) trifluoromethanesulfonate, 98%, Thermo Scientific Chemicals
Catalog number: B20253.06
5 g, Each
Thermo Scientific Chemicals
Copper(II) trifluoromethanesulfonate, 98%, Thermo Scientific Chemicals
Catalog number: B20253.06
5 g, Each
Quantity
Catalog number: B20253.06
also known as B20253-06
Price (EUR)
73,44 Online price
81,60
Each
Quantity
-
Chemical Identifiers
CAS
34946-82-2
IUPAC Name
copper(II) triflate
Molecular Formula
C2H2CuF6O4S2
InChI Key
TXWAGEFXPDWAQH-UHFFFAOYSA-N
SMILES
[Cu].FC(F)(F)S(=O)=O.FC(F)(F)S(=O)=O
Specifications
Specification SheetAssay (Iodometric Titration)
≥97.5 to ≤102.5%
Appearance (Color)
White to pale cream to pale green or pale blue to pale gray
Form
Powder
Description
Copper(II) trifluoromethanesulfonate acts as a catalyst in Diels-Alder reaction and cyclopropanation reactions. It is also used as a reagent for oligosaccharide synthesis. It acts as a Lewis acid. It is also employed in the dimerization of ketone enolates and tetramethylsilane enol ethers. It is used to prepare cis vinylic sulfones and oxazoles from alkynyl sulfones and ketones respectively. Further, it plays an important role for cyclization of dienolates. In addition to this, it is useful for dehydration of alcohols.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Applications
Copper(II) trifluoromethanesulfonate acts as a catalyst in Diels-Alder reaction and cyclopropanation reactions. It is also used as a reagent for oligosaccharide synthesis. It acts as a Lewis acid. It is also employed in the dimerization of ketone enolates and tetramethylsilane enol ethers. It is used to prepare cis vinylic sulfones and oxazoles from alkynyl sulfones and ketones respectively. Further, it plays an important role for cyclization of dienolates. In addition to this, it is useful for dehydration of alcohols.
Solubility
Soluble in water.
Notes
Hygroscopic. Incompatible with strong oxidizing agents.
Copper(II) trifluoromethanesulfonate acts as a catalyst in Diels-Alder reaction and cyclopropanation reactions. It is also used as a reagent for oligosaccharide synthesis. It acts as a Lewis acid. It is also employed in the dimerization of ketone enolates and tetramethylsilane enol ethers. It is used to prepare cis vinylic sulfones and oxazoles from alkynyl sulfones and ketones respectively. Further, it plays an important role for cyclization of dienolates. In addition to this, it is useful for dehydration of alcohols.
Solubility
Soluble in water.
Notes
Hygroscopic. Incompatible with strong oxidizing agents.
RUO – Research Use Only
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Safety and Handling
Classification of the substance or mixture
CLP classification - Regulation(EC) No 1272/2008
Skin Corrosion/Irritation
Category 1
Serious Eye Damage/Eye Irritation
Category 1
Label Elements
Signal Word
Danger
Hazard Statements
H314 - Causes severe skin burns and eye damage
Precautionary Statements
P280 - Wear protective gloves/protective clothing/eye protection/face protection
P301 + P330 + P331 - IF SWALLOWED: Rinse mouth. Do NOT induce vomiting
P303 + P361 + P353 - IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower
P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
P310 - Immediately call a POISON CENTER or doctor/physician