Thermo Scientific Chemicals

4-Morpholinylsulfur trifluoride, 95%, Thermo Scientific Chemicals

Catalog number: L19751.06
5 g, Each
Thermo Scientific Chemicals

4-Morpholinylsulfur trifluoride, 95%, Thermo Scientific Chemicals

Catalog number: L19751.06
5 g, Each
Quantity
Catalog number: L19751.06
also known as L19751-06
Price (EUR)
Quantity
-

Chemical Identifiers

CAS
51010-74-3
IUPAC Name
4-(trifluoro-λ⁴-sulfanyl)morpholine
Molecular Formula
C4H8F3NOS
InChI Key
UFXIRMVZNARBDL-UHFFFAOYSA-N
SMILES
FS(F)(F)N1CCOCC1
Appearance (Color)
Clear colorless to yellow
Refractive Index
1.4515-1.4575 @ 20?C
Assay (Non-aqueous acid-base Titration)
≥94.0 to ≤106.0%
Form
Liquid

Description

4-Morpholinylsulfur trifluoride is incorporated in the fluoronation of trihexanols. It is used as a nucleophilic fluorinating agent with greater thermal stability. It is also used in the preparation of proline analogs and in the preparation of difluoropiperidines.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
4-Morpholinylsulfur trifluoride is incorporated in the fluoronation of trihexanols. It is used as a nucleophilic fluorinating agent with greater thermal stability. It is also used in the preparation of proline analogs and in the preparation of difluoropiperidines.

Solubility
Reacts with water.

Notes
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Incompatible with bases and oxidizing and bases. Store under dry inert gas. It is sensitive to moisture.
RUO – Research Use Only

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    Safety and Handling


    Classification of the substance or mixture
    CLP classification - Regulation(EC) No 1272/2008
    Skin Corrosion/Irritation
    Category 1
    Serious Eye Damage/Eye Irritation
    Category 1
    Label Elements
    Signal Word

    Danger

    Hazard Statements

    H314 - Causes severe skin burns and eye damage

    EU Specific Hazard Statements

    Combustible liquid

    EUH014 - Reacts violently with water

    Precautionary Statements

    P280 - Wear protective gloves/protective clothing/eye protection/face protection

    P301 + P330 + P331 - IF SWALLOWED: Rinse mouth. Do NOT induce vomiting

    P303 + P361 + P353 - IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower

    P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing

    P310 - Immediately call a POISON CENTER or doctor/physician