Thermo Scientific Chemicals

Dicarbonyl(2,4-pentanedionato)rhodium(I), 97%, Thermo Scientific Chemicals

Catalog number: 039295.06
5 g, Each
Thermo Scientific Chemicals

Dicarbonyl(2,4-pentanedionato)rhodium(I), 97%, Thermo Scientific Chemicals

Catalog number: 039295.06
5 g, Each
Quantity
Catalog number: 039295.06
also known as 039295-06
Price (EUR)

Chemical Identifiers

CAS
14874-82-9
IUPAC Name
λ¹-rhodium(1+) bis(methanidylidyneoxidanium) (2Z)-4-oxopent-2-en-2-olate
Molecular Formula
C7H7O4Rh
InChI Key
BZCAWKOPWNIDOC-FGSKAQBVSA-M
SMILES
[Rh+].[C-]#[O+].[C-]#[O+].C\C([O-])=C\C(C)=O
Assay (unspecified)
≤96.0%
Appearance (Color)
Green
Form
Crystalline powder or powder

Description

(Acetylacetonato)dicarbonylrhodium(I) is used in in situ formation of a floors-soluble hydroformylation catalyst of interest in molecular engineering. It is also used as a catalyst for various carbonylation reactions, silylcarbocyclizations, conjugate additions to eons, carbamoylstannation, and reduction of aromatic nitro compounds. It is also used in Hydroformylation reaction.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

RUO – Research Use Only

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    Safety and Handling


    Classification of the substance or mixture
    CLP classification - Regulation(EC) No 1272/2008
    Flammable solids
    Category 2
    Acute oral toxicity
    Category 3
    Serious Eye Damage/Eye Irritation
    Category 2
    Skin Sensitization
    Category 1
    Chronic aquatic toxicity
    Category 3
    Label Elements
    Signal Word

    Danger

    Hazard Statements

    H301 - Toxic if swallowed

    H317 - May cause an allergic skin reaction

    H319 - Causes serious eye irritation

    H412 - Harmful to aquatic life with long lasting effects

    Physical Hazards

    H228 - Flammable solid

    EU Specific Hazard Statements

    EUH044 - Risk of explosion if heated under confinement

    Precautionary Statements

    P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking

    P280 - Wear protective gloves/protective clothing/eye protection/face protection

    P301 + P310 - IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician

    P302 + P352 - IF ON SKIN: Wash with plenty of soap and water

    P333 + P313 - If skin irritation or rash occurs: Get medical advice/attention

    P337 + P313 - If eye irritation persists: Get medical advice/attention