Thermo Scientific Chemicals

Sodium thiocyanate, 96%, Thermo Scientific Chemicals

Catalog number: A11867.0B
1000 g, Each
Thermo Scientific Chemicals

Sodium thiocyanate, 96%, Thermo Scientific Chemicals

Catalog number: A11867.0B
1000 g, Each
Quantity
Catalog number: A11867.0B
also known as A11867-0B
Price (EUR)
Quantity
-

Chemical Identifiers

CAS
540-72-7
IUPAC Name
sodium cyanosulfanide
Molecular Formula
CNNaS
InChI Key
VGTPCRGMBIAPIM-UHFFFAOYSA-M
SMILES
[Na+].[S-]C#N
Form
Crystals or powder or crystalline powder or fused/lumpy solid or chunks
Assay (Argentometric Titration)
≥95.0 to ≤105.0%
Water Content (Karl Fischer Titration)
≤5.0%
Appearance (Color)
White

Description

A compound used to convert alkyl halides into the corresponding alkylthiocyanates. Undergoes nucleophilic substitution reactions with phase-transfer catalysts. Silver thiocyanate may be used as well, the precipitation of insoluble silver halides help simplify workup. Treatment of isopropyl bromide with sodium thiocyanate in a hot ethanolic solution affords isopropyl thiocyanate.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
A compound used to convert alkyl halides into the corresponding alkylthiocyanates. Undergoes nucleophilic substitution reactions with phase-transfer catalysts. Silver thiocyanate may be used as well, the precipitation of insoluble silver halides help simplify workup. Treatment of isopropyl bromide with sodium thiocyanate in a hot ethanolic solution affords isopropyl thiocyanate.

Solubility
Soluble in water (1250g/L), alcohol, and acetone.

Notes
Hygroscopic, protect from humidity and water. Store in cool, dry conditions in well sealed container.
RUO – Research Use Only

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    Safety and Handling


    Classification of the substance or mixture
    CLP classification - Regulation(EC) No 1272/2008
    Acute oral toxicity
    Category 4
    Acute dermal toxicity
    Category 4
    Acute Inhalation Toxicity - Vapors
    Category 4
    Acute Inhalation Toxicity - Dusts and Mists
    Category 4
    Chronic aquatic toxicity
    Category 3
    Label Elements
    Signal Word

    Warning

    Hazard Statements

    H302 + H312 + H332 - Harmful if swallowed, in contact with skin or if inhaled

    H412 - Harmful to aquatic life with long lasting effects

    EU Specific Hazard Statements

    EUH032 - Contact with acids liberates very toxic gas

    Precautionary Statements

    P233 - Keep container tightly closed

    P273 - Avoid release to the environment

    P301 + P312 - IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell

    P304 + P340 - IF INHALED: Remove person to fresh air and keep comfortable for breathing

    P280 - Wear protective gloves/protective clothing/eye protection/face protection

    P302 + P352 - IF ON SKIN: Wash with plenty of soap and water