Thermo Scientific Chemicals

1-Formylpiperidine, 99%, Thermo Scientific Chemicals

Catalog number: B23452.0B
1000 g, Each
Thermo Scientific Chemicals

1-Formylpiperidine, 99%, Thermo Scientific Chemicals

Catalog number: B23452.0B
1000 g, Each
Quantity
Catalog number: B23452.0B
also known as B23452-0B
Price (EUR)
Quantity
-

Chemical Identifiers

CAS
2591-86-8
IUPAC Name
piperidine-1-carbaldehyde
Molecular Formula
C6H11NO
InChI Key
FEWLNYSYJNLUOO-UHFFFAOYSA-N
SMILES
O=CN1CCCCC1
Appearance (Color)
Clear colorless
Assay (GC)
≥98.5%
Refractive Index
1.4830-1.4860 @ 20?C
Form
Liquid

Description

1-Formylpiperidine reacts with Grignard or alkyllithium reagents gives aldehydes in high yield. It can be used as a polar aprotic solvent, with better hydrocarbon solubility than other amide solvents such as dimethylformamide. In some formylation reaction of alkyllithium compounds it gives higher yields than the DMF.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
1-Formylpiperidine reacts with Grignard or alkyllithium reagents gives aldehydes in high yield. It can be used as a polar aprotic solvent, with better hydrocarbon solubility than other amide solvents such as dimethylformamide. In some formylation reaction of alkyllithium compounds it gives higher yields than the DMF.

Solubility
Freely soluble in water.

Notes
Incompatible materials are oxidizing agents. Store in cool place. Keep container tightly closed in a dry and well-ventilated place.
RUO – Research Use Only

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    Safety and Handling


    Classification of the substance or mixture
    CLP classification - Regulation(EC) No 1272/2008
    Acute oral toxicity
    Category 4
    Acute dermal toxicity
    Category 3
    Skin Corrosion/Irritation
    Category 2
    Serious Eye Damage/Eye Irritation
    Category 2
    Specific target organ toxicity - (single exposure)
    Category 3
    Label Elements
    Signal Word

    Danger

    Hazard Statements

    H302 - Harmful if swallowed

    H311 - Toxic in contact with skin

    H315 - Causes skin irritation

    H319 - Causes serious eye irritation

    H335 - May cause respiratory irritation

    EU Specific Hazard Statements

    Combustible liquid

    Precautionary Statements

    P310 - Immediately call a POISON CENTER or doctor/physician

    P264 - Wash face, hands and any exposed skin thoroughly after handling

    P270 - Do not eat, drink or smoke when using this product

    P280 - Wear protective gloves/protective clothing/eye protection/face protection

    P302 + P352 - IF ON SKIN: Wash with plenty of soap and water

    P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing