Thermo Scientific Chemicals

Vinylboronic anhydride pyridine complex, 95%, Thermo Scientific Chemicals

Catalog number: H28703.03
1 g, Each
Thermo Scientific Chemicals

Vinylboronic anhydride pyridine complex, 95%, Thermo Scientific Chemicals

Catalog number: H28703.03
1 g, Each
Quantity
Catalog number: H28703.03
also known as H28703-03
Price (EUR)
Quantity
-

Chemical Identifiers

CAS
95010-17-6
IUPAC Name
pyridine; triethenyl-1,3,5,2,4,6-trioxatriborinane
Molecular Formula
C11H14B3NO3
InChI Key
YLHJACXHRQQNQR-UHFFFAOYSA-N
SMILES
C1=CC=NC=C1.C=CB1OB(OB(O1)C=C)C=C
Appearance (Color)
White to cream or pale yellow
Proton NMR
Conforms to structure
Assay by NMR
>94.0%
Form
Crystalline powder

Description

Reagent used for Suzuki-Miyaura cross-coupling, stereoselective synthesis via Palladium-catalyzed carboamination, Alkyl-connected 2-amino-6-vinylpurine (AVP) cross linking agent to cytosine base in RNA, Kaiser oxime resin-derived palladacycle as a recoverable polymeric precatalyst in Suzuki-Miyaura cross-coupling reactions in aqueous media and Kinetic resolution of phosphoryl and sulfonyl esters of binaphthol derivatives via Pd-catalyzed alcoholysis of their vinyl ethers.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Reagent used for Suzuki-Miyaura cross-coupling, stereoselective synthesis via Palladium-catalyzed carboamination, Alkyl-connected 2-amino-6-vinylpurine (AVP) cross linking agent to cytosine base in RNA, Kaiser oxime resin-derived palladacycle as a recoverable polymeric precatalyst in Suzuki-Miyaura cross-coupling reactions in aqueous media and Kinetic resolution of phosphoryl and sulfonyl esters of binaphthol derivatives via Pd-catalyzed alcoholysis of their vinyl ethers.

Solubility
Soluble in methanol.

Notes
Moisture Sensitive, store away from water/moisture. Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store under dry inert gas.
RUO – Research Use Only

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    Safety and Handling


    Classification of the substance or mixture
    CLP classification - Regulation(EC) No 1272/2008
    Flammable solids
    Category 2
    Acute oral toxicity
    Category 4
    Acute dermal toxicity
    Category 4
    Acute Inhalation Toxicity - Dusts and Mists
    Category 4
    Skin Corrosion/Irritation
    Category 2
    Serious Eye Damage/Eye Irritation
    Category 2
    Specific target organ toxicity - (single exposure)
    Category 3
    Label Elements
    Signal Word

    Warning

    Hazard Statements

    H302 + H312 + H332 - Harmful if swallowed, in contact with skin or if inhaled

    H315 - Causes skin irritation

    H319 - Causes serious eye irritation

    H335 - May cause respiratory irritation

    Physical Hazards

    H228 - Flammable solid

    Precautionary Statements

    P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking

    P280 - Wear protective gloves/protective clothing/eye protection/face protection

    P301 + P330 + P331 - IF SWALLOWED: rinse mouth. Do NOT induce vomiting

    P302 + P352 - IF ON SKIN: Wash with plenty of soap and water

    P304 + P340 - IF INHALED: Remove person to fresh air and keep comfortable for breathing

    P312 - Call a POISON CENTER or doctor if you feel unwell

    P332 + P313 - If skin irritation occurs: Get medical advice/attention

    P337 + P313 - If eye irritation persists: Get medical advice/attention