Phosphorous acid, 98+%, Thermo Scientific Chemicals
Phosphorous acid, 98+%, Thermo Scientific Chemicals
Thermo Scientific Chemicals

Phosphorous acid, 98+%, Thermo Scientific Chemicals

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Catalog number A11189.30
also known as A11189-30
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Chemical Identifiers
CAS13598-36-2
IUPAC Namedihydroxy(oxo)-λ⁵-phosphanylium
Molecular FormulaH2O3P
InChI KeyXNQULTQRGBXLIA-UHFFFAOYSA-O
SMILESO[P+](O)=O
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SpecificationsSpecification SheetSpecification Sheet
Assay (Aqueous acid-base Titration)≥98.0 to ≤102.0%
FormFlakes or crystals or crystalline powder or powder
Water Content (Karl Fischer Titration)<1.5%
Appearance (Color)White to pale cream
Identification (FTIR)Conforms
Phosphorus acid is used as an intermediate in the preparation of other phosphorus compounds like potassium phosphite, ammonium phosphite and calcium phosphite. It is actively involved in the preparation of phosphites like aminotris(methylenephosphonic acid) (ATMP), 1-hydroxyethane 1,1-diphosphonic acid (HEDP) and 2-phosphonobutane-1,2,4-tricarboxylic Acid (PBTC), which find application in water treatment as a scale or corrosive inhibitor. It is also used in chemical reactions as a reducing agent. Its salt, lead phosphite is used as PVC stabilizer. It is also used as precursor in the preparation of phosphine as well as an intermediate in the preparation of other phosphorus compounds.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Phosphorus acid is used as an intermediate in the preparation of other phosphorus compounds like potassium phosphite, ammonium phosphite and calcium phosphite. It is actively involved in the preparation of phosphites like aminotris(methylenephosphonic acid) (ATMP), 1-hydroxyethane 1,1-diphosphonic acid (HEDP) and 2-phosphonobutane-1,2,4-tricarboxylic Acid (PBTC), which find application in water treatment as a scale or corrosive inhibitor. It is also used in chemical reactions as a reducing agent. Its salt, lead phosphite is used as PVC stabilizer. It is also used as precursor in the preparation of phosphine as well as an intermediate in the preparation of other phosphorus compounds.

Solubility
Soluble in water and alcohol.

Notes
Air sensitive. Hygroscopic. Incompatible with strong bases, oxidizing agents and metals.
RUO – Research Use Only

General References:

  1. Prokop, M.; Bystron, T.; Bouzek, K. Electrochemistry of phosphorus and Hypophosphorus Acid on a Pt electrode. Electrochim. Acta 2015, 160, 214-218.
  2. Grun, A.; Kovacs, R.; Illes Nagy, D.; Garadnay, S.; Greiner, I.; Keglevich, G. Efficient Synthesis of Benzidronate Applying of Phosphorus Trichloride and phosphorus Acid. Lett Drug Des Discov 2015, 12 (1), 78-84.