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4-Bromotoluene, 98%, Thermo Scientific ChemicalsHave Questions?
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化學識別
CAS106-38-7
IUPAC Name1-bromo-4-methylbenzene
Molecular FormulaC7H7Br
InChI KeyZBTMRBYMKUEVEU-UHFFFAOYSA-N
SMILESCC1=CC=C(Br)C=C1
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規格表4-Bromotoluene was used in the synthesis of ketones by Cu/Pd-catalyzed decarboxylative cross-coupling reaction. 4-Bromotoluene undergoes Heck reaction with styrene in the presence of in situ generated palladium complexes of phosphine-functionalized N-heterocyclic carbene ligands.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Applications
4-Bromotoluene was used in the synthesis of ketones by Cu/Pd-catalyzed decarboxylative cross-coupling reaction. 4-Bromotoluene undergoes Heck reaction with styrene in the presence of in situ generated palladium complexes of phosphine-functionalized N-heterocyclic carbene ligands.
Solubility
Insoluble in water. Soluble in methanol.
Notes
Store at room temperature. Keep away from oxidizing agents.
4-Bromotoluene was used in the synthesis of ketones by Cu/Pd-catalyzed decarboxylative cross-coupling reaction. 4-Bromotoluene undergoes Heck reaction with styrene in the presence of in situ generated palladium complexes of phosphine-functionalized N-heterocyclic carbene ligands.
Solubility
Insoluble in water. Soluble in methanol.
Notes
Store at room temperature. Keep away from oxidizing agents.
RUO – Research Use Only
General References:
- Louis-Charles Campeau.; Sophie Rousseaux.; Keith Fagnou. A Solution to the 2-Pyridyl Organometallic Cross-Coupling Problem: Regioselective Catalytic Direct Arylation of Pyridine N-Oxides. J. Am. Chem. Soc. 2005, 127 (51),18020-18021 .
- Janis Louie.; John F. Hartwig. Discrete High Molecular Weight Triarylamine Dendrimers Prepared by Palladium-Catalyzed Amination.J. Am. Chem. Soc. 1997, 119 (48),11695-11696 .