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Iodosobenzene diacetate, 98+%, Thermo Scientific Chemicals
產品號碼: B24531.22
100 g, Each
化學識別
CAS
3240-34-4
IUPAC Name
(acetyloxy)(phenyl)-λ³-iodanyl acetate
Molecular Formula
C10H11IO4
InChI Key
ZBIKORITPGTTGI-UHFFFAOYSA-N
SMILES
CC(=O)O[I](OC(C)=O)C1=CC=CC=C1
規格
規格表Appearance (Color)
White
Form
Crystals or powder or crystalline powder
Assay (Iodometric Titration)
≥98.0 to ≤102.0%
Identification (FTIR)
Conforms
說明
Iodosobenzene is used as an oxidizing and acetoxylating agent in organic synthesis. It is actively involved in the preparation of (Z)-3,7-dimethyl-2,6-octadien-1-al(neral) from (Z)-3,7-dimethyl-2,6-octadien-1-ol (nerol) in presence of 2,2,6,6-tetramethylpiperidin-1-oxyl (TEMPO). It is a useful reagent for the synthesis of a wide variety of heterocyclic compounds. It is also used in the Pd-catalyzed 2-arylation of indoles.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Applications
Iodosobenzene is used as an oxidizing and acetoxylating agent in organic synthesis. It is actively involved in the preparation of (Z)-3,7-dimethyl-2,6-octadien-1-al(neral) from (Z)-3,7-dimethyl-2,6-octadien-1-ol (nerol) in presence of 2,2,6,6-tetramethylpiperidin-1-oxyl (TEMPO). It is a useful reagent for the synthesis of a wide variety of heterocyclic compounds. It is also used in the Pd-catalyzed 2-arylation of indoles.
Solubility
Insoluble in water.
Notes
Light sensitive. Incompatible with strong oxidizing agents.
Iodosobenzene is used as an oxidizing and acetoxylating agent in organic synthesis. It is actively involved in the preparation of (Z)-3,7-dimethyl-2,6-octadien-1-al(neral) from (Z)-3,7-dimethyl-2,6-octadien-1-ol (nerol) in presence of 2,2,6,6-tetramethylpiperidin-1-oxyl (TEMPO). It is a useful reagent for the synthesis of a wide variety of heterocyclic compounds. It is also used in the Pd-catalyzed 2-arylation of indoles.
Solubility
Insoluble in water.
Notes
Light sensitive. Incompatible with strong oxidizing agents.
RUO – Research Use Only
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