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Thermo Scientific Chemicals
Phenylmagnesium bromide, 3M in 2-MeTHF, Thermo Scientific Chemicals
化學識別
CAS100-58-3
IUPAC Namebromo(phenyl)magnesium
Molecular FormulaC6H5BrMg
InChI KeyANRQGKOBLBYXFM-UHFFFAOYSA-M
SMILESBr[Mg]C1=CC=CC=C1
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規格表Phenyl magnesium bromide is the suitable reagent used for the synthesis of end-functionalized regioregular poly(3-alkylthiophene)s. It may be used for synthesis of 1,3,3-trimethyl-6-phenyl-2-oxabicyclo[2.2.2]octan-6-ol, 6-benzyl-1,3,3-trimethyl-2-oxabicyclo[2.2.2]octan-6-ol, (3-(2-Dithiobenzoatepropionyl)propyl)dimethylmethoxysilane, reversible addition-fragmentation chain transfer polymerization (RAFT)-silane agent, series of o-substituted benzophenones.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Applications
Phenyl magnesium bromide is the suitable reagent used for the synthesis of end-functionalized regioregular poly(3-alkylthiophene)s. It may be used for synthesis of 1,3,3-trimethyl-6-phenyl-2-oxabicyclo[2.2.2]octan-6-ol, 6-benzyl-1,
Phenyl magnesium bromide is the suitable reagent used for the synthesis of end-functionalized regioregular poly(3-alkylthiophene)s. It may be used for synthesis of 1,3,3-trimethyl-6-phenyl-2-oxabicyclo[2.2.2]octan-6-ol, 6-benzyl-1,
RUO – Research Use Only
General References:
- W. H. Urry.; M. S. Kharasch. Factors Influencing the Course and Mechanism of Grignard Reactions. XV. The Reaction of β,β-Dimethylphenethyl Chloride with Phenylmagnesium Bromide in the Presence of Cobaltous Chloride. J. Am. Chem. Soc. 1944, 66 (9),1438-1440.
- G. Stucky.; R. E. Rundle. The Constitution of the Grignard Reagent, Phenylmagnesium Bromide Dietherate. J. Am. Chem. Soc. 1964, 87 (22),4825-4830.