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2-Bromo-4-fluoro-1-iodobenzene, 98+%, Thermo Scientific Chemicals
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化學識別
CAS202865-73-4
IUPAC Name2-bromo-4-fluoro-1-iodobenzene
Molecular FormulaC6H3BrFI
InChI KeyGKGPZAZTXZCUMU-UHFFFAOYSA-N
SMILESFC1=CC(Br)=C(I)C=C1
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規格
規格表
規格表Assay (GC)≥98.0%
Appearance (Color)Clear pale yellow to yellow or pink
Refractive Index1.6275-1.6315 @ 20?C
FormLiquid
It is employed in the synthesis of tetrasubstituted alkenes by stereo- and regioselective stannyllithiation of diarylacetylenes.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Applications
It is employed in the synthesis of tetrasubstituted alkenes by stereo- and regioselective stannyllithiation of diarylacetylenes.
Solubility
Not miscible or difficult to mix in water.
Notes
Light sensitive. Store away from oxidizing agents. Keep the container tightly closed and place it in a cool, dry and well ventilated condition. Store in dark.
It is employed in the synthesis of tetrasubstituted alkenes by stereo- and regioselective stannyllithiation of diarylacetylenes.
Solubility
Not miscible or difficult to mix in water.
Notes
Light sensitive. Store away from oxidizing agents. Keep the container tightly closed and place it in a cool, dry and well ventilated condition. Store in dark.
RUO – Research Use Only
General References:
- Hayato Tsuji, et al. Synthesis of Tetrasubstituted Alkenes by Stereo- and Regioselective Stannyllithiation of Diarylacetylenes.J. Am. Chem. Soc.,2010,132(34), 11854-11855.
- Akio Kamimura, et al. Pd-Catalyzed Tandem sp2-sp3 Coupling Reactions of Chiral Stannolanes: An Efficient Preparation of Optically Active Tetrahydrobenz[f]isoindoles.Org. Lett.,2013,15(6), 1402-1405.