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Ethyl hydrogen malonate, 96%, Thermo Scientific Chemicals
製品番号（カタログ番号）： A12627.18
50 g, Each
化学物質識別子
CAS
1071-46-1
IUPAC Name
3-ethoxy-3-oxopropanoic acid
Molecular Formula
C5H8O4
InChI Key
HGINADPHJQTSKN-UHFFFAOYSA-N
SMILES
CCOC(=O)CC(O)=O
仕様
スペックシートAppearance (Color)
Clear colorless to pale yellow
Assay (Aqueous acid-base Titration)
≥95.0 to ≤105.0%
Refractive Index
1.4245-1.4320 @ 20?C
Water Content (Karl Fischer Titration)
≤2%
Form
Liquid
概要
Ethyl hydrogen malonate is used as a reactant for the preparation of tetramic acids through Dieckmann ring closure and organocatalytic decarboxylative Doebner-Knoevenagel reactions. It is involved in the acylation reactions and Knoevenagel condensation with aldehydes. It is also used in the preparation of gamma-lactones from olefins by intermolecular carbolactonization in presence of Mn(III) acetate as a catalyst.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Applications
Ethyl hydrogen malonate is used as a reactant for the preparation of tetramic acids through Dieckmann ring closure and organocatalytic decarboxylative Doebner-Knoevenagel reactions. It is involved in the acylation reactions and Knoevenagel condensation with aldehydes. It is also used in the preparation of gamma-lactones from olefins by intermolecular carbolactonization in presence of Mn(III) acetate as a catalyst.
Solubility
Miscible with water, chloroform and other solvents.
Notes
Incompatible with strong oxidizing agents.
Ethyl hydrogen malonate is used as a reactant for the preparation of tetramic acids through Dieckmann ring closure and organocatalytic decarboxylative Doebner-Knoevenagel reactions. It is involved in the acylation reactions and Knoevenagel condensation with aldehydes. It is also used in the preparation of gamma-lactones from olefins by intermolecular carbolactonization in presence of Mn(III) acetate as a catalyst.
Solubility
Miscible with water, chloroform and other solvents.
Notes
Incompatible with strong oxidizing agents.
RUO – Research Use Only
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