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Phenyl vinyl sulfone, 99+%, Thermo Scientific Chemicals
化学物質識別子
CAS5535-48-8
IUPAC Name(ethenesulfonyl)benzene
Molecular FormulaC8H8O2S
InChI KeyUJTPZISIAWDGFF-UHFFFAOYSA-N
SMILESC=CS(=O)(=O)C1=CC=CC=C1
さらに表示
仕様
スペックシート
スペックシートFormCrystals or powder or crystalline powder
Appearance (Color)White to cream to pale brown
Identification (FTIR)Conforms
Assay (GC)≥98.5%
Melting Point (clear melt)65.0-72.0°C
Phenyl vinyl sulfone is used as building blocks in the synthesis of a number of organic substances, participate in polymerization reactions, nucleophilic addition reaction, and in cycloaddition reactions. It is also used in the used in the synthesis of reactive dyes, synthesis of textile fibers, in particular cellulose fibers such as cotton and linen. Other applications in the field of medicine includes as powerful inhibitors of certain enzymatic processes. It is an important raw material and intermediate used in organic synthesis, pharmaceuticals, agrochemicals and dye stuff.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Applications
Phenyl vinyl sulfone is used as building blocks in the synthesis of a number of organic substances, participate in polymerization reactions, nucleophilic addition reaction, and in cycloaddition reactions. It is also used in the used in the synthesis of reactive dyes, synthesis of textile fibers, in particular cellulose fibers such as cotton and linen. Other applications in the field of medicine includes as powerful inhibitors of certain enzymatic processes. It is an important raw material and intermediate used in organic synthesis, pharmaceuticals, agrochemicals and dye stuff.
Solubility
It is soluble in most common organic solvents.
Notes
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Stable under recommended storage conditions. Keep away from strong oxidizing agents.
Phenyl vinyl sulfone is used as building blocks in the synthesis of a number of organic substances, participate in polymerization reactions, nucleophilic addition reaction, and in cycloaddition reactions. It is also used in the used in the synthesis of reactive dyes, synthesis of textile fibers, in particular cellulose fibers such as cotton and linen. Other applications in the field of medicine includes as powerful inhibitors of certain enzymatic processes. It is an important raw material and intermediate used in organic synthesis, pharmaceuticals, agrochemicals and dye stuff.
Solubility
It is soluble in most common organic solvents.
Notes
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Stable under recommended storage conditions. Keep away from strong oxidizing agents.
RUO – Research Use Only
General References:
- Franklin A. Davis.; Sankar G. Lal.; H. Dupont Durst. Chemistry of oxaziridines. 10. Selective catalytic oxidation of sulfides to sulfoxides using N-sulfonyloxaziridines. J. Org. Chem. 1988, 53, (21), 5004-5007.K Grela .; M Bieniek. Highly selective cross-metathesis with phenyl vinyl sulphone using the 'second generation'Grubbs' catalyst. Tetrahedron Letters. 2001, 42, (36), 6425-6428.
- Reactive dienophile. Can function as an acetylene equivalent if benzenesulfinic acid is eliminated thermally from the Diels-Alder adduct to form an olefinic double bond: J. Am. Chem. Soc., 100, 1597 (1978).
- Can also behave as an activated form of ethylene if the sulfone group is cleaved from the adduct, e.g. with Na amalgam, with the possibility of prior alkylation of the adduct: J. Org. Chem., 48, 4976 (1983):
- For addition to 1-Methoxy-3-trimethyl siloxy-1,3-butadiene, L06100, see: J. Org. Chem., 48, 4986 (1983). Addition to steroids with a cyclopentadienoid D-ring, followed by cleavage of the resulting alkene, gives the diformyl derivatives, useful for further functionalization: J. Chem. Soc., Perkin 1, 241 (1990).
- For use in a 1,3-dipolar cycloaddition reaction, see 3-Hydroxypyridine, A13910.
- Undergoes the Baylis-Hillman reaction (addition to aldehydes in the presence of 1,4-Diazabicyclo[2.2.2]octane, A14003): Tetrahedron, 44, 6095 (1988).
- See also Divinyl sulfone, L12827.