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2-Bromo-4,6-dimethylaniline, 98%, Thermo Scientific Chemicals
化学物質識別子
CAS41825-73-4
仕様
スペックシート
スペックシートAppearance (Color)Cream to brown
FormCrystals or powder or crystalline powder or pellets
Assay (GC)≥97.5%
Water Content (Karl Fischer Titration)≤1%
Melting Point (clear melt)41.0-47.0?C
2-Bromo-4,6-dimethylaniline can react with 3-chloro-3-methyl-but-1-yne to produce 2-bromo-N-(1',1'-dimethylprop-2'-ynyl)-4,6-dimethylaniline. This reaction will need reagent Et3N, catalyst CuCl, and the menstruum dioxane.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Applications
2-Bromo-4,6-dimethylaniline can react with 3-chloro-3-methyl-but-1-yne to produce 2-bromo-N-(1′,1′-dimethylprop-2′-ynyl)-4,6-dimethylaniline. This reaction will need reagent Et3N, catalyst CuCl, and the menstruum dioxane.
Solubility
Insoluble in water.
Notes
Keep container tightly closed. Store away from oxidizing agents.
2-Bromo-4,6-dimethylaniline can react with 3-chloro-3-methyl-but-1-yne to produce 2-bromo-N-(1′,1′-dimethylprop-2′-ynyl)-4,6-dimethylaniline. This reaction will need reagent Et3N, catalyst CuCl, and the menstruum dioxane.
Solubility
Insoluble in water.
Notes
Keep container tightly closed. Store away from oxidizing agents.
RUO – Research Use Only
General References:
- Rattan K. Gujadhur.; Craig G. Bates.; D. Venkataraman. Formation of Aryl-Nitrogen, Aryl-Oxygen, and Aryl-Carbon Bonds Using Well-Defined Copper(I)-Based Catalysts. Org. Lett. 2001, 3, (26), 4315-4317.
- Fuk Yee Kwong.; Artis Klapars.; Stephen L. Buchwald. Copper-Catalyzed Coupling of Alkylamines and Aryl Iodides: An Efficient System Even in an Air Atmospheres. Org. Lett. 2002, 4, (4), 581-584.