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Iron(III) trifluoromethanesulfonate, tech. 90%, Thermo Scientific Chemicals
化学物質識別子
CAS63295-48-7
IUPAC Nameiron(3+) tritrifluoromethanesulfonate
Molecular FormulaC3F9FeO9S3
InChI KeyOSHOQERNFGVVRH-UHFFFAOYSA-K
SMILES[Fe+3].[O-]S(=O)(=O)C(F)(F)F.[O-]S(=O)(=O)C(F)(F)F.[O-]S(=O)(=O)C(F)(F)F
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仕様
スペックシート
スペックシートAssay (Titration)>88.0%
Iron(III) triflate is used as an efficient catalyst in the synthesis of 2,3-unsaturated-O-glycosides from 2,4,6-tri-O-acetyl-D-glucal. It is also involved in the synthesis of a variety of beta-enamino ketones and esters.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Applications
Iron(III) triflate is used as an efficient catalyst in the synthesis of 2,3-unsaturated-O-glycosides from 2,4,6-tri-O-acetyl-D-glucal. It is also involved in the synthesis of a variety of beta-enamino ketones and esters.
Solubility
Soluble in water, methanol and acetonitrile.
Notes
Moisture sensitive. Keep container tightly closed in a dry and well-ventilated place. Incompatible with strong oxidizing agents.
Iron(III) triflate is used as an efficient catalyst in the synthesis of 2,3-unsaturated-O-glycosides from 2,4,6-tri-O-acetyl-D-glucal. It is also involved in the synthesis of a variety of beta-enamino ketones and esters.
Solubility
Soluble in water, methanol and acetonitrile.
Notes
Moisture sensitive. Keep container tightly closed in a dry and well-ventilated place. Incompatible with strong oxidizing agents.
RUO – Research Use Only
General References:
- Xolin, A.; Stevenin, A.; Pucheault, M.; Norsikian, S.; Boyer, F. D.; Beau, J. M. Glycosylation with N-acetyl glycosamine donors using catalytic iron (iii) triflate: from microwave batch chemistry to a scalable continuous-flow process. Org Chem Front 2014, 1 (8), 992-1000.
- Feng, C. L.; Chu, N. N.; Zhang, S. G.; Cai, J.; Chen, J. Q.; Hu, H. Y.; Ji, M. Solvent-free synthesis of beta-enamino ketones and esters catalysed by recyclable iron (III) triflate. Chem. Pap. 2014, 68 (8), 1097-1103.