Thermo Scientific Chemicals

Pinacolborane, 97%, Thermo Scientific Chemicals

製品番号(カタログ番号): L17558.06
5 g, Each
Thermo Scientific Chemicals

Pinacolborane, 97%, Thermo Scientific Chemicals

製品番号(カタログ番号): L17558.06
5 g, Each
数量
製品番号(カタログ番号): L17558.06
または、製品番号L17558-06

化学物質識別子

CAS
25015-63-8
IUPAC Name
4,4,5,5-tetramethyl-1,3,2-dioxaborolane
Molecular Formula
C6H13BO2
InChI Key
UCFSYHMCKWNKAH-UHFFFAOYSA-N
SMILES
CC1(C)OBOC1(C)C
Refractive Index
1.3940-1.4000 @ 20?C
Appearance (Color)
Clear colorless
Form
Liquid
Assay from Supplier's CofA
≥96.0%

概要

Pinacolborane is used as a precursor of boronic esters by hydroboration or coupling reactions. It acts as a monofunctional hydroborating agent. It is used in the synthesis of unsymmetrical biaryls through aromatic C-H borylation-cross-coupling sequence. It is involved in the preparation of 4,4,5,5-tetramethyl-2-thiophen-2-yl-[1,3,2]dioxaborolane by reacting with 2-iodo-thiophene. Further, it is used to prepare vinylboronates by palladium-catalyzed coupling with alkenyl triflates and iodides.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Pinacolborane is used as a precursor of boronic esters by hydroboration or coupling reactions. It acts as a monofunctional hydroborating agent. It is used in the synthesis of unsymmetrical biaryls through aromatic C-H borylation-cross-coupling sequence. It is involved in the preparation of 4,4,5,5-tetramethyl-2-thiophen-2-yl-[1,3,2]dioxaborolane by reacting with 2-iodo-thiophene. Further, it is used to prepare vinylboronates by palladium-catalyzed coupling with alkenyl triflates and iodides.

Solubility
Miscible with ether, dichloromethane, tetrahydrofuran and organic solvents.

Notes
Air sensitive and moisture sensitive. Store in a cool place. Keep the container tightly closed in a dry and well-ventilated place. Incompatible with strong oxidizing agents, strong acids, water, bases and alcohols.
RUO – Research Use Only

ドキュメントおよびダウンロード

証明書

    よくあるご質問(FAQ)

    引用および参考文献

    Search citations by name, author, journal title or abstract text